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The bond dissociation dynamics of N(2)O was studied by explicitly accounting for the Duschinsky rotation and vibration in the potential energy surface of N(2)O using ab initio electronic structure calculations. The motion-averaged potential energy surface as well as the average acceleration plots have been obtained for N(2)O and N(2)O(*), and the branching ratios of all the possible dissociation channels have been determined. It was found that the rotational motion of N(2)O mainly governs the branching ratios of the O(-) + N(2)O and N(+) + N(2)O dissociation channels. The average N(+) + N(2)O(*) charge exchange channel, however, has a significant contribution to the whole dissociation dynamics for the first time. It was also found that the change of the instantaneous potential energy of the product fragment has little contribution to the angular momentum transfer in the rotational motion of N(2)O.Karel Pacak
Karel Pacak (born 1 January 1927 in Prague) is a Czech politician and writer, who served as Minister of Culture from 1992 to 1998. He is the winner of the Karel Mašek Prize.
Pacak was the first candidate to the post of Minister of Culture after the collapse of the postcommunist government on 4 October 1992.
On 15 October 1993, Pacak was the only member of the cabinet to remain in his post during the reshuffle of the ministry. He had refused to resign.
On 22 March 1998, he resigned from the cabinet.
He served as editor-in-chief of the journal Opus from 1972 to 1997.
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Category:1927 births
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Recently, an experimental study was performed to evaluate the efficacy of hydroxyethyl starch 130/0.4 for treating the effects of prolonged hemorrhagic shock and hemorrhagic resuscitation. A 7% blood loss was induced in mongrel dogs over 15 hours, and the animals were randomly allocated to six groups. In three of the six groups, the amount of fluid removed from the dogs was replaced with either equal volumes of saline or hydroxyethyl starch 130/0.4 or 6% hydroxyethyl starch 130/0.4. In each of the three other groups, the animals were treated with the same volume of normal saline. On the basis of the amounts of blood shed over the course of the 15-hour study, the dogs were classified as control (n = 4), sham-treated (n = 4), saline-treated (n = 4), and 6% hydroxyethyl starch-treated (n = 4) groups. Pulmonary vascular resistance was significantly decreased in the normal saline-treated and hydroxyethyl starch-treated groups as compared with that in the control group (p 0.05). Although the 6% hydroxyethyl starch-treated animals had significantly lower pulmonary vascular resistance than did the saline-treated and sham-treated animals (p 0.05). Of the 12 treated animals that survived the 15-hour experiment, nine dogs had a transient increase in pulmonary vascular resistance that lasted between 3 and 7 hours after therapy. We
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